Table 1
Classification and labelling of the solvent according to ECHA/REACH documentation.
| Solvent | Hexane | Iso-Hx | Cycl Hex | MeOH | EtOH | IPA | Acetone | MEK | EA | DCM | 2-MeOx | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| CAS RN | 110-54-3 | 107-83-5 | 110-82-74 | 67-56-1 | 64-17-5 | 67-63-0 | 67-64-1 | 78-93-3 | 141-78-6 | 75-09-2 | 96-47-9 | |
| Occupational Exposure Limit (ECHA, ppm) | 20 | 200 | – | – | 500 | 200 | 200 | 100 | ||||
| France VLE /8h (ppm, molar) | 20 | 500 | 200 | 200 | 1000 | (400 CT) | 500 | 200 | 200 | 50 | ||
| Germany (MAK) | 50 | 500 | 200 | 200 | 200 | 500 | ||||||
Flammable  |
||||||||||||
Acute toxicity  |
||||||||||||
Health hazard  |
||||||||||||
Nocive or irrit.  |
||||||||||||
Envion. hazard  |
||||||||||||
Corrosive  |
||||||||||||
| Properties of concern | Repro-toxic * | Cancer ** | Cancer + endoc*** | |||||||||
| LD 50 oral (g/kg) | 0.024-0.049 | 0.0158 | 5 | 1.19-2.77 | 1.18 − 15.0 | 5.84 | 5.8 | 2-6 | 10.19 | 2 | 0.3 | |
| Flam. Liq. 2 | H225 | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | R | ||
| Acute Tox. 3 | H301 | ✔ | ||||||||||
| Acute Tox. 4 | H302 | R | n | R | ||||||||
| Asp. Tox. 1 | H304 | ✔ | ✔ | ✔ | ||||||||
| Acute Tox. 3 | H311 | ✔ | ||||||||||
| Skin Irritant 2 | H315 | ✔ | ✔ | ✔ | n | R | R | |||||
| Eye dam. 1 | H318 | R | ||||||||||
| Eye Irritant 2 | H319 | R | n | R | ✔ | ✔ | ✔ | ✔ | R | n | ||
| Acute Tox. 3 | H331 | ✔ | ||||||||||
| STOT SE 3 | H335 | n | n | n | n | n | ||||||
| STOT SE 3 | H336 | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | ✔ | R | n | ||
| Mutagen 2 | H341 | n | ||||||||||
| Carcinogen. B1 | H350 | R | ||||||||||
| Carcinogen. 2 | H351 | n | ✔ | |||||||||
| Reprotoxic 2 | H361f | ✔ | ||||||||||
| STOT SE 1 | H370 | ✔ | R | |||||||||
| STOT SE 2 | H371 | R | n | |||||||||
| STOT RE 1 | H372 | n | ||||||||||
| STOT RE 2 | H373 | ✔ | n | |||||||||
| Aquatic Ac. 1 | H400 | n | ✔ | |||||||||
| Aquatic Chr 1 | H410 | n | ✔ | |||||||||
| Aquatic Ch 2 | H411 | ✔ | ✔ | |||||||||
(*) suspected to be toxic to reproduction; (**) Some submitters consider as carcinogenic; (***) Suspected carcinogenic & under assessment for endocrine disruption.
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