Open Access
Table 3
Activity of catalytic peroxo-complexes on the oxidative scission (Godard et al., 2013a, b).
| Catalyst system | X− | χOA | YAA | YAP |
| (%) | (%) | (%) | ||
| 38.1 | 1.8 | 2.2 | ||
[MeN(n-C8H PO4 [WO(O |
Cl− | 100 | 75.7 | 80.7 |
| [
n-Bu4N]3 {PO4 [WO(O |
Cl− | 100 | 77.6 | 80.9 |
[
(n-C8H N]
3 {PO4 [WO(O |
Cl− | 100 | 73.2 | 76.5 |
| [C5H5N(n-C16H33) ] 3
{PO4
[WO(O |
Cl− | 100 | 81.5 | 86.1 |
Conditions: AO/H2O2/Q3{PO4[WO(O2)2]4} (1/5/0,02), 85 °C, 5 h, 400 rpm. Standard deviation (3 analyses) between 0.1 to 3.9%.
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